The major components of wood ashes are potassium carbonate (potash) and sodium carbonate (soda ash).
Whatever we extract from wood ashes must be there to begin with. Wood ashes are a complex heterogeneous mixture of all the non-flammable, non-volatile minerals which remain after the wood and charcoal have burned away. Because of the presence of carbon dioxide in the fire gases, many of these minerals will have been converted to carbonates. Burned soil may also be present. So the ashes probably contain predominately sodium and potassium carbonate, sodium and potassium chloride, silica, and calcium carbonate.
If we add the ashes to water, the soluble potassium and sodium salts will dissolve while the insoluble silica and calcium carbonate will settle to the bottom. We can then drain off the water (containing the “good stuff”) and throw the insoluble material away.
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